Doping-induced structural transformation in the spin-1/2 triangular-lattice antiferromagnet Na2Ba1-xSrxCo(PO4)2

نویسندگان

چکیده

The effects of Sr doping on the structural properties Na2BaCo(PO4)2, a spin-1/2 triangular-lattice antiferromagnet as quantum spin liquid candidate, are investigated by complementary x-ray and neutron powder diffraction measurements. It is found that in Na2Ba1−xSrxCo(PO4)2 (NBSCPO), trigonal phase (space group P3̅m1) with perfect triangular lattice Co2+ ions structurally stable when level below 30% (x ≤ 0.3), while pure monoclinic P21/a) slight rotations CoO6 octahedra displacements Ba2+/Sr2+ will be established above 60% ≥ 0.6). Such doping-induced transformation NBSCPO supported first-principles calculations Raman spectroscopy. Na2SrCo(PO4)2, novel glaserite-type structure, although monoclinically distorted, exhibits no long-range magnetic order down to 2 K similar negative Curie-Weiss temperature Na2BaCo(PO4)2 lattice, suggesting robustness exchange interaction against Ba/Sr substitutions.

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ژورنال

عنوان ژورنال: Journal of Alloys and Compounds

سال: 2022

ISSN: ['0925-8388', '1873-4669']

DOI: https://doi.org/10.1016/j.jallcom.2022.164147